Supramolecular assembly of a quasi-linear heterofullerene-porphyrin dyad

Hauke F, Swartz A, Guldi DM, Hirsch A, Hauke F (2002)


Publication Language: English

Publication Type: Journal article, Original article

Publication year: 2002

Journal

Original Authors: Hauke F., Swartz A., Guldi D.M., Hirsch A.

Publisher: Royal Society of Chemistry

Book Volume: 12

Pages Range: 2088-2094

Journal Issue: 7

DOI: 10.1039/b202060b

Abstract

A novel supramolecular dyad (Zn-ttbpp-pyridine-CN) - with a quasi-linear geometry - involving a heterofullerene acceptor and a zinc tetrakis(p-tert-butylphenyl)porphyrin (Zn-ttbpp) donor was assembled via axial coordination. Depending on the solvent either photoinduced singlet-singlet energy transfer or electron transfer was observed. The latter process takes place in o-dichlorobenzene as solvent and leads to the corresponding charge-separated state, that is, the π-radical anion of CN and the π-radical cation of Zn-ttbpp.

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How to cite

APA:

Hauke, F., Swartz, A., Guldi, D.M., Hirsch, A., & Hauke, F. (2002). Supramolecular assembly of a quasi-linear heterofullerene-porphyrin dyad. Journal of Materials Chemistry, 12(7), 2088-2094. https://dx.doi.org/10.1039/b202060b

MLA:

Hauke, Frank, et al. "Supramolecular assembly of a quasi-linear heterofullerene-porphyrin dyad." Journal of Materials Chemistry 12.7 (2002): 2088-2094.

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