Stereospecific carbene polymerization with oxygenated Rh(diene) species
Walters AJ, Tröppner O, Ivanovic-Burmazovic I, Tejel C, del Rio MP, Reek JN, De Bruin B (2012)
Publication Type: Journal article, Original article
Publication year: 2012
Journal
Original Authors: Walters A., Troeppner O., Ivanović-Burmazović I., Tejel C., Del Río M., Reek J., De Bruin B.
Publisher: Wiley-VCH Verlag
Book Volume: 51
Pages Range: 5157-5161
Journal Issue: 21
Abstract
Breath-taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)Rh -polymeryl] species. These are most efficiently generated by oxygenation of the [(diene)Rh ] precatalysts, which involves an unusual rearrangement of 2-rhodaoxetane intermediates. This discovery gives detailed insight in the reaction mechanism. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Authors with CRIS profile
Oliver Tröppner
Lehrstuhl für Bioanorganische Chemie
Ivana Ivanovic-Burmazovic
Lehrstuhl für Bioanorganische Chemie
Involved external institutions
Netherlands (NL)How to cite
APA:
Walters, A.J., Tröppner, O., Ivanovic-Burmazovic, I., Tejel, C., del Rio, M.P., Reek, J.N., & De Bruin, B. (2012). Stereospecific carbene polymerization with oxygenated Rh(diene) species. Angewandte Chemie International Edition, 51(21), 5157-5161. https://doi.org/10.1002/anie.201200069
MLA:
Walters, Annemarie J.C., et al. "Stereospecific carbene polymerization with oxygenated Rh(diene) species." Angewandte Chemie International Edition 51.21 (2012): 5157-5161.
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