Analysis of optical absorbance spectra for the determination of ZnO nanoparticle size distribution, solubility, and surface energy

Segets D, Gradl J, Klupp Taylor R, Vassilev V, Peukert W (2009)


Publication Language: English

Publication Type: Journal article

Publication year: 2009

Journal

Book Volume: 3

Pages Range: 1703-1710

Journal Issue: 7

DOI: 10.1021/nn900223b

Abstract

We present a model to calculate particle size distributions (PSDs) of colloidal ZnO nanoparticles from their absorbance spectra. Using literature values for the optical properties of bulk ZnO and correlating the measurement wavelengths in the UV−visible regime with distinct particle sizes by a tight binding model (TBM), an algorithm deconvolutes the absorbance spectra into contributions from size fractions. We find an excellent agreement between size distributions determined from TEM images and the calculated PSDs. For further validation, bimodal PSDs have been investigated and an approach to determine not only particle size but also solid concentration is introduced. We will show the applicability of our model by the determination of temperature-dependent ripening rates, which enables the calculation of solubilities, surface tensions, and the activation enthalpy of ripening. In principle, our methodology is applicable to different semiconductor nanoparticles in various solvents as long as their bulk properties are known and scattering is negligible.

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APA:

Segets, D., Gradl, J., Klupp Taylor, R., Vassilev, V., & Peukert, W. (2009). Analysis of optical absorbance spectra for the determination of ZnO nanoparticle size distribution, solubility, and surface energy. Acs Nano, 3(7), 1703-1710. https://dx.doi.org/10.1021/nn900223b

MLA:

Segets, Doris, et al. "Analysis of optical absorbance spectra for the determination of ZnO nanoparticle size distribution, solubility, and surface energy." Acs Nano 3.7 (2009): 1703-1710.

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