Isomerisation of 1,4-dichlorobenzene using highly acidic alkali chloroaluminate melts.

Journal article
(Original article)


Publication Details

Author(s): Meßner J, Schulz P, Taccardi N, Kuhlmann S, Wasserscheid P
Journal: Chemical Communications
Publisher: Royal Society of Chemistry
Publication year: 2014
Volume: 50
Journal issue: 79
Pages range: 11705-11708
ISSN: 1359-7345


Abstract


The isomerization reaction of 1,4-dichlorobenzene leading to the thermodynamically favored and tech. desired 1,3-dichlorobenzene has been studied comparing highly acidic chloroaluminate melts with org. imidazolium and alkali metal ions. Interestingly, the inorg. melts show much higher reactivity and full recyclability if small AlCl3 losses are compensated and the reaction is carried out under slight HCl pressure. [on SciFinder(R)]



FAU Authors / FAU Editors

Meßner, Julia
Lehrstuhl für Chemische Reaktionstechnik
Schulz, Peter Dr.
Lehrstuhl für Chemische Reaktionstechnik
Taccardi, Nicola Dr.
Lehrstuhl für Chemische Reaktionstechnik
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik


External institutions with authors

LANXESS AG


How to cite

APA:
Meßner, J., Schulz, P., Taccardi, N., Kuhlmann, S., & Wasserscheid, P. (2014). Isomerisation of 1,4-dichlorobenzene using highly acidic alkali chloroaluminate melts. Chemical Communications, 50(79), 11705-11708.

MLA:
Meßner, Julia, et al. "Isomerisation of 1,4-dichlorobenzene using highly acidic alkali chloroaluminate melts." Chemical Communications 50.79 (2014): 11705-11708.

BibTeX: 

Last updated on 2018-10-08 at 02:10