Isomerisation of 1,4-dichlorobenzene using highly acidic alkali chloroaluminate melts.

Meßner J, Schulz P, Taccardi N, Kuhlmann S, Wasserscheid P (2014)

Publication Type: Journal article, Original article

Subtype: other

Publication year: 2014

Journal

Chemical Communications Royal Society of Chemistry

Publisher: Royal Society of Chemistry

Book Volume: 50

Pages Range: 11705-11708

Journal Issue: 79

Abstract

The isomerization reaction of 1,4-dichlorobenzene leading to the thermodynamically favored and tech. desired 1,3-dichlorobenzene has been studied comparing highly acidic chloroaluminate melts with org. imidazolium and alkali metal ions. Interestingly, the inorg. melts show much higher reactivity and full recyclability if small AlCl3 losses are compensated and the reaction is carried out under slight HCl pressure. [on SciFinder(R)]

Authors with CRIS profile

Julia Meßner Lehrstuhl für Chemische Reaktionstechnik Peter Schulz Lehrstuhl für Chemische Reaktionstechnik Nicola Taccardi Lehrstuhl für Chemische Reaktionstechnik Peter Wasserscheid Lehrstuhl für Chemische Reaktionstechnik

Involved external institutions

LANXESS AG DE Germany (DE)

How to cite

APA:

Meßner, J., Schulz, P., Taccardi, N., Kuhlmann, S., & Wasserscheid, P. (2014). Isomerisation of 1,4-dichlorobenzene using highly acidic alkali chloroaluminate melts. Chemical Communications, 50(79), 11705-11708.

MLA:

Meßner, Julia, et al. "Isomerisation of 1,4-dichlorobenzene using highly acidic alkali chloroaluminate melts." Chemical Communications 50.79 (2014): 11705-11708.

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