Is bis(trifluoromethylsulfonyl)amide an innocent anion? X-ray structure data and DFT calculations.

Illner P, Puchta R, Heinemann FW, van Eldik R (2009)

Publication Status: Published

Publication Type: Journal article

Publication year: 2009

Journal

Dalton Transactions Royal Society of Chemistry

Pages Range: 2795-2801

Journal Issue: 15

DOI: 10.1039/b820940e

Abstract

The coordinative behaviour of the bis(trifluoromethylsulfonyl)amide (NTf2-) anion was studied in terms of its interaction with the labile [Pd(terpyridine)Cl]Cl complex. Among various attempts to coordinate NTf2- to the Pd(II) centre, the complexes [Pd(terpyridine)NO3]NTf2 and [Pd(terpyridine)H2O](NTf2)2 were isolated and characterized. The crystallographic data for these complexes are presented and the possible coordination of the NTf2- anion to the metal centre is discussed in reference to DFT predictions.

Authors with CRIS profile

Ralph Puchta Naturwissenschaftliche Fakultät Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Rudi van Eldik Naturwissenschaftliche Fakultät

How to cite

APA:

Illner, P., Puchta, R., Heinemann, F.W., & van Eldik, R. (2009). Is bis(trifluoromethylsulfonyl)amide an innocent anion? X-ray structure data and DFT calculations. Dalton Transactions, 15, 2795-2801. https://dx.doi.org/10.1039/b820940e

MLA:

Illner, Peter, et al. "Is bis(trifluoromethylsulfonyl)amide an innocent anion? X-ray structure data and DFT calculations." Dalton Transactions 15 (2009): 2795-2801.

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