[CpArNi{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2)
Chakraborty U, Muehldorf B, Van Velzen NJC, De Bruin B, Harder S, Wolf R (2016)
Publication Type: Journal article
Publication year: 2016
Journal
Book Volume: 55
Pages Range: 3075-3078
Journal Issue: 6
DOI: 10.1021/acs.inorgchem.5b02979
Abstract
The 17 valence electron (VE) open-shell nickel gallanediyl
complex [CpArNi{Ga(nacnac)}] (3, Ar = C5(C6H4-4-Et)5, nacnac = HC[C(Me)-
N(C6H3-2,6-iPr2)]2), having an unsupported Ni−Ga bond, was synthesized from
[CpArNi(μ-Br)]2 (1) by reducing the adduct [CpArNi(μ-Br){Ga(nacnac)}] (2)
or, alternatively, trapping the “CpArNiI” synthon with Ga(nacnac); spectroscopic
and DFT studies showed that the single unpaired electron in 3 resides mainly at
the Ni center.
Low-
Authors with CRIS profile
Involved external institutions
Universität Regensburg
Germany (DE)
University of Groningen / Rijksuniversiteit Groningen
Netherlands (NL)
University of Amsterdam
Netherlands (NL)
Germany (DE)
University of Groningen / Rijksuniversiteit Groningen
Netherlands (NL)
University of Amsterdam
Netherlands (NL)
How to cite
APA:
Chakraborty, U., Muehldorf, B., Van Velzen, N.J.C., De Bruin, B., Harder, S., & Wolf, R. (2016). [CpArNi{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2). Inorganic Chemistry, 55(6), 3075-3078. https://doi.org/10.1021/acs.inorgchem.5b02979
MLA:
Chakraborty, Uttam, et al. "[CpArNi{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2)." Inorganic Chemistry 55.6 (2016): 3075-3078.
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