[CpArNi{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2)

Journal article


Publication Details

Author(s): Chakraborty U, Muehldorf B, Van Velzen NJC, De Bruin B, Harder S, Wolf R
Journal: Inorganic Chemistry
Publication year: 2016
Volume: 55
Journal issue: 6
Pages range: 3075-3078
ISSN: 1520-510X


Abstract


The 17 valence electron (VE) open-shell nickel gallanediyl

complex [CpArNi{Ga(nacnac)}] (3, Ar = C5(C6H4-4-Et)5, nacnac = HC[C(Me)-

N(C6H3-2,6-iPr2)]2), having an unsupported Ni−Ga bond, was synthesized from

[CpArNi(μ-Br)]2 (1) by reducing the adduct [CpArNi(μ-Br){Ga(nacnac)}] (2)

or, alternatively, trapping the “CpArNiI” synthon with Ga(nacnac); spectroscopic

and DFT studies showed that the single unpaired electron in 3 resides mainly at

the Ni center.

Low-



FAU Authors / FAU Editors

Harder, Sjoerd Prof. Dr.
Professur für Anorganische Chemie


External institutions with authors

Universität Regensburg
University of Amsterdam
University of Groningen / Rijksuniversiteit Groningen


How to cite

APA:
Chakraborty, U., Muehldorf, B., Van Velzen, N.J.C., De Bruin, B., Harder, S., & Wolf, R. (2016). [CpArNi{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2). Inorganic Chemistry, 55(6), 3075-3078. https://dx.doi.org/10.1021/acs.inorgchem.5b02979

MLA:
Chakraborty, Uttam, et al. "[CpArNi{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2)." Inorganic Chemistry 55.6 (2016): 3075-3078.

BibTeX: 

Last updated on 2018-06-08 at 21:38