Protonation of Ferrocene: A Low-Temperature X-ray Diffraction Study of [Cp2 FeH](PF6 ) Reveals an Iron-Bound Hydrido Ligand.

Malischewski M, Seppelt K, Sutter J, Heinemann FW, Dittrich B, Meyer K (2017)


Publication Status: Published

Publication Type: Journal article

Publication year: 2017

Journal

Book Volume: 56

Pages Range: 13372-13376

Journal Issue: 43

DOI: 10.1002/anie.201704854

Abstract

Ferrocene, Cp2Fe, is quantitatively protonated in a mixture of liquid HF/PF5 to yield [Cp2FeH](PF6), which was characterized by H-1/(CNMR)-C-13 and Fe-57 Mossbauer spectroscopy as well as single-crystal X-ray diffraction analysis. X-ray diffraction analysis at 100K revealed a disordered, iron-coordinated hydrido ligand, which was unambiguously located by aspherical atom refinement at 100K, and by analyzing the non-disordered crystal structure at 30K, revealing a non-agostic structure.

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APA:

Malischewski, M., Seppelt, K., Sutter, J., Heinemann, F.W., Dittrich, B., & Meyer, K. (2017). Protonation of Ferrocene: A Low-Temperature X-ray Diffraction Study of [Cp2 FeH](PF6 ) Reveals an Iron-Bound Hydrido Ligand. Angewandte Chemie International Edition, 56(43), 13372-13376. https://dx.doi.org/10.1002/anie.201704854

MLA:

Malischewski, Moritz, et al. "Protonation of Ferrocene: A Low-Temperature X-ray Diffraction Study of [Cp2 FeH](PF6 ) Reveals an Iron-Bound Hydrido Ligand." Angewandte Chemie International Edition 56.43 (2017): 13372-13376.

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