Basic Insights into Tunable Graphene Hydrogenation

Journal article
(Original article)


Publication Details

Author(s): Schäfer R, Dasler D, Mundloch U, Hauke F, Hirsch A
Journal: Journal of the American Chemical Society
Publisher: American Chemical Society
Publication year: 2016
Volume: 138
Journal issue: 5
Pages range: 1647-52
ISSN: 1520-5126
Language: English


Abstract


The hydrogenation and deuteration of graphite with potassium intercalation compounds as starting materials were investigated in depth. Characterization of the reaction products (hydrogenated and deuterated graphene) was carried out by thermogravimetric analysis coupled with mass spectrometry (TG-MS) and statistical Raman spectroscopy (SRS) and microscopy (SRM). The results reveal that the choice of the hydrogen/deuterium source, the nature of the graphite (used as starting material), the potassium concentration in the intercalation compound, and the choice of the solvent have a great impact on the reaction outcome. Furthermore, it was possible to prove that both mono- and few-layer hydrogenated/deuterated graphene can be produced.



FAU Authors / FAU Editors

Dasler, Daniela
Sonderforschungsbereich 953/2 Synthetische Kohlenstoffallotrope
Hauke, Frank Dr.
Zentralinstitut für Neue Materialien und Prozesstechnik
Hirsch, Andreas Prof. Dr.
Lehrstuhl für Organische Chemie II
Mundloch, Udo
Lehrstuhl für Organische Chemie II
Schäfer, Ricarda
Lehrstuhl für Organische Chemie II


Additional Organisation
Exzellenz-Cluster Engineering of Advanced Materials


How to cite

APA:
Schäfer, R., Dasler, D., Mundloch, U., Hauke, F., & Hirsch, A. (2016). Basic Insights into Tunable Graphene Hydrogenation. Journal of the American Chemical Society, 138(5), 1647-52. https://dx.doi.org/10.1021/jacs.5b11994

MLA:
Schäfer, Ricarda, et al. "Basic Insights into Tunable Graphene Hydrogenation." Journal of the American Chemical Society 138.5 (2016): 1647-52.

BibTeX: 

Last updated on 2018-16-06 at 00:23