Vines Solana F, Desikusumastuti A, Staudt T, Görling A, Libuda J, Neyman KM (2008)
Publication Type: Journal article, Original article
Publication year: 2008
Original Authors: Vines F., Desikusumastuti A., Staudt T., Görling A., Libuda J., Neyman K.M.
Publisher: American Chemical Society
Book Volume: 112
Pages Range: 16539-16549
Journal Issue: 42
DOI: 10.1021/jp804315c
Nanocrystalline particles expose special adsorption sites close to edges and corners, giving rise to novel adsorption and reaction properties. The spectroscopic identification of these sites represents a great challenge, however. Here, we present results of a combined experimental and theoretical study on the adsorption of NO on Pd nanoparticles, using infrared reflection absorption spectroscopy (IRAS) and calculations based on density-functional theory (DFT). This approach facilitates identification of the adsorption sites available on the nanoparticles and reveals detailed information on their bonding properties, on the vibrational parameters of NO adsorbed on these sites, and on their sequence of occupation. With respect to all these aspects, the adsorption behavior of NO on the Pd nanoparticles notably differs from any single crystal reference data available. The IRAS studies are performed on well-defined Pd nanoparticles supported on an ordered AlO film on NiAl(110). The growth and structure of these particles has been characterized previously, predominately exposing (111) and a small fraction of (100) facets. Here, we systematically monitor the NO adsorption as a function of exposure in a temperature region between 100 and 300 K by means of time-resolved IRAS in combination with molecular beam (MB) dosing. We interpret these experimental data with the help of DFT calculations on the adsorption of NO on unsupported cuboctahedral Pd clusters cut from Pd bulk and containing up to 140 atoms; for comparison, calculations of the reference adsorption complexes of NO on single-crystal Pd(111) surface have also been performed. NO molecules are shown to most favorably adsorb on hollow μ-sites on (111) facets of Pd clusters, closely followed by bridge μ-sites at the edges between adjacent (111) facets. Both sites give rise to characteristic features in the vibrational spectrum and are populated sequentially. At higher coverage (and low temperature) on-top μ-sites on the (111) facets begin to be occupied. At variance with the adsorption on Pd(111) surface, however, additional on-top-sites are available at the particle edges and corners, which reveal stronger NO adsorption. In spite of the strong adsorption in bridge (μ) coordination geometry at edges, our calculations predict that intermolecular repulsion between adjacent μ-NO species gives rise to the formation of mixed bridge/on-top structures at high coverage. Similarly to the bridge NO at particle edges, the edge- and corner-related μ-NO species reveal characteristic vibrational frequencies, allowing for direct verification of this prediction by IRAS. The present results make possible the identification and monitoring of the occupation of specific sites on Pd nanoparticles by NO during adsorption and reaction processes. © 2008 American Chemical Society.
APA:
Vines Solana, F., Desikusumastuti, A., Staudt, T., Görling, A., Libuda, J., & Neyman, K.M. (2008). A combined density-functional and IRAS study on the interaction of NO with Pd nanoparticles: Identifying new adsorption sites with novel properties. Journal of Physical Chemistry C, 112(42), 16539-16549. https://dx.doi.org/10.1021/jp804315c
MLA:
Vines Solana, Francesc, et al. "A combined density-functional and IRAS study on the interaction of NO with Pd nanoparticles: Identifying new adsorption sites with novel properties." Journal of Physical Chemistry C 112.42 (2008): 16539-16549.
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