Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60

Elemes Y, Hirsch A, Ioannou J (2007)


Publication Type: Journal article, Original article

Publication year: 2007

Journal

Original Authors: Ioannou E., Hirsch A., Elemes Y.

Publisher: Elsevier

Book Volume: 63

Pages Range: 7070-7076

Journal Issue: 30

DOI: 10.1016/j.tet.2007.05.011

Abstract

C reacts thermally with 1,3-dipoles, formed in situ, from sulfide-bearing imines of glycine esters, and affords dihydro-pyrrolo [60]fullerene derivatives containing a vinylic sulfide group, which were isolated in good yields, and characterized with H and C NMR, FTIR, UV-vis spectroscopies, and with FAB, ESI mass spectrometries. The new derivatives contain a sulfide, an imine, and an ester functionality for further chemical transformations. Mechanistic considerations with regard to the loss of a mercaptan molecule in the course of the cycloaddition are deployed. © 2007 Elsevier Ltd. All rights reserved.

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APA:

Elemes, Y., Hirsch, A., & Ioannou, J. (2007). Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60. Tetrahedron, 63(30), 7070-7076. https://doi.org/10.1016/j.tet.2007.05.011

MLA:

Elemes, Yiannis, Andreas Hirsch, and John Ioannou. "Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60." Tetrahedron 63.30 (2007): 7070-7076.

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