Improving the Charge Transport in Self-Assembled Monolayer Field-Effect Transistors: From Theory to Devices
Jäger C, Schmaltz T, Novak M, Khassanov A, Vorobiev A, Hennemann M, Krause A, Dietrich H, Zahn D, Hirsch A, Halik M, Clark T (2013)
Publication Language: English
Publication Type: Journal article, Original article
Publication year: 2013
Journal
Original Authors: Jäger C.M., Schmaltz T., Novak M., Khassanov A., Vorobiev A., Hennemann M., Krause A., Dietrich H., Zahn D., Hirsch A., Halik M., Clark T.
Publisher: American Chemical Society
Book Volume: 135
Pages Range: 4893-4900
Journal Issue: 12
DOI: 10.1021/ja401320n
Abstract
A three-pronged approach has been used to design rational improvements in self-assembled monolayer field-effect transistors: classical molecular dynamics (MD) simulations to investigate atomistic structure, large-scale quantum mechanical (QM) calculations for electronic properties, and device fabrication and characterization as the ultimate goal. The MD simulations reveal the effect of using two-component monolayers to achieve intact dielectric insulating layers and a well-defined semiconductor channel. The QM calculations identify improved conduction paths in the monolayers that consist of an optimum mixing ratio of the components. These results have been used both to confirm the predictions of the calculations and to optimize real devices. Monolayers were characterized with X-ray reflectivity measurements and by electronic characterization of complete devices. © 2013 American Chemical Society.
Authors with CRIS profile
Christof Jäger
Computer-Chemie-Centrum
Thomas Schmaltz
Professur für Werkstoffwissenschaften (Polymerwerkstoffe)
Artöm Khassanov
Professur für Werkstoffwissenschaften (Polymerwerkstoffe)
Matthias Hennemann
Computer-Chemie-Centrum
Andreas Krause
Interdisziplinäres Zentrum für Molekulare Materialien
Hanno Dietrich
Computer-Chemie-Centrum
Dirk Zahn
Professur für Theoretische Chemie
Andreas Hirsch
Lehrstuhl für Organische Chemie II
Marcus Halik
Professur für Werkstoffwissenschaften (Polymerwerkstoffe)
Timothy Clark
Computer-Chemie-Centrum
Additional Organisation(s)
Involved external institutions
France (FR)How to cite
APA:
Jäger, C., Schmaltz, T., Novak, M., Khassanov, A., Vorobiev, A., Hennemann, M.,... Clark, T. (2013). Improving the Charge Transport in Self-Assembled Monolayer Field-Effect Transistors: From Theory to Devices. Journal of the American Chemical Society, 135(12), 4893-4900. https://dx.doi.org/10.1021/ja401320n
MLA:
Jäger, Christof, et al. "Improving the Charge Transport in Self-Assembled Monolayer Field-Effect Transistors: From Theory to Devices." Journal of the American Chemical Society 135.12 (2013): 4893-4900.
BibTeX: Download