Stereospecific Ligands and their Complexes. III. Oxalato and Malonato-(ethylenediamine-N,N '-di-S,S-2-propionato)-Chromate(III) Complexes. Crystal Structure of the Delta-(-)(589)-s-cis-K[Cr(S,S-eddp)(ox)] center dot 0.5H(2)O
Glodjovic VV, Heinemann FW, Trifunovic SR (2008)
Publication Status: Published
Publication Type: Journal article
Publication year: 2008
Journal
Publisher: SPRINGER/PLENUM PUBLISHERS
Book Volume: 38
Pages Range: 883-889
Journal Issue: 12
DOI: 10.1007/s10870-008-9400-4
Abstract
The s-cis-[Cr(S,S-eddp)L](-) complexes (S,S-eddp = S,S-ethylenediamine-N,N'-di-2-propionate ion; L = oxalate or malonate ions) were prepared. The complexes were purified by ion-exchange chromatography. The geometry of the complexes has been supposed on the basis of the electronic absorption spectra, and the absolute configurations of the isolated s-cis-[Cr(S,S-eddp)L](-) complexes have been predicted on the basis of their circular dichroism (CD) spectra and confirmed by X-ray analysis of the crystal structure of the Delta-(-)(589)-s-cis-K[Cr(S,S-eddp)(ox)] 0.5H(2)O complex.
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APA:
Glodjovic, V.V., Heinemann, F.W., & Trifunovic, S.R. (2008). Stereospecific Ligands and their Complexes. III. Oxalato and Malonato-(ethylenediamine-N,N '-di-S,S-2-propionato)-Chromate(III) Complexes. Crystal Structure of the Delta-(-)(589)-s-cis-K[Cr(S,S-eddp)(ox)] center dot 0.5H(2)O. Journal of Chemical Crystallography, 38(12), 883-889. https://doi.org/10.1007/s10870-008-9400-4
MLA:
Glodjovic, Verica V., Frank Wilhelm Heinemann, and Srecko R. Trifunovic. "Stereospecific Ligands and their Complexes. III. Oxalato and Malonato-(ethylenediamine-N,N '-di-S,S-2-propionato)-Chromate(III) Complexes. Crystal Structure of the Delta-(-)(589)-s-cis-K[Cr(S,S-eddp)(ox)] center dot 0.5H(2)O." Journal of Chemical Crystallography 38.12 (2008): 883-889.
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