Palladium(II) complexes with R(2)edda-derived ligands. Part V. Reaction of O,O '-diethyl-(S,S)-ethylenediamine-N,N '-di-2-(3-methyl)butanoate with K-2[PdCl4]

Radic GP, Glodovic VV, Kaluderovic GN, Heinemann FW, Trifunovic SR (2011)

Publication Status: Published

Publication Type: Journal article

Publication year: 2011

Journal

Transition Metal Chemistry Springer Verlag (Germany)

Publisher: SPRINGER

Book Volume: 36

Pages Range: 331-336

Journal Issue: 4

DOI: 10.1007/s11243-011-9473-3

Abstract

The reaction of K-2[PdCl4] with [(S,S)-H-2(Et)(2)eddv]Cl-2 diester (O,O'-diethyl-(S,S)-ethylenediamine-N,N'-di(2)-(3-methyl)butanoate) (1) resulted in [PdCl2{(S, S)-(Et) eddv-kappa N-2,N', kappa O}] (2) complex with one hydrolyzed ester group. The compound was characterized by spectroscopic methods and it was found that the reaction is diastereoselective (H-1 and C-13 NMR; one diastereoisomer of four possible). In addition, the structure of 2 was confirmed by X-ray diffraction analysis, indicating that the product is the (R,R)-N,N'-configured isomer. DFT calculations support the formation of one diastereoisomer of 2.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

University of Kragujevac RS Serbia (RS) Martin-Luther-Universität Halle-Wittenberg (MLU) DE Germany (DE)

How to cite

APA:

Radic, G.P., Glodovic, V.V., Kaluderovic, G.N., Heinemann, F.W., & Trifunovic, S.R. (2011). Palladium(II) complexes with R(2)edda-derived ligands. Part V. Reaction of O,O '-diethyl-(S,S)-ethylenediamine-N,N '-di-2-(3-methyl)butanoate with K-2[PdCl4]. Transition Metal Chemistry, 36(4), 331-336. https://dx.doi.org/10.1007/s11243-011-9473-3

MLA:

Radic, Gordana P., et al. "Palladium(II) complexes with R(2)edda-derived ligands. Part V. Reaction of O,O '-diethyl-(S,S)-ethylenediamine-N,N '-di-2-(3-methyl)butanoate with K-2[PdCl4]." Transition Metal Chemistry 36.4 (2011): 331-336.

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