Syntheses, characterization, and reactivity of copper complexes with tridentate N-donor ligands

Astner J, Weitzer M, Foxon SP, Schindler S, Heinemann FW, Mukherjee J, Gupta R, Mahadevan V, Mukherjee R (2008)

Publication Status: Published

Publication Type: Journal article

Publication year: 2008

Journal

Inorganica Chimica Acta Elsevier

Publisher: ELSEVIER SCIENCE SA

Book Volume: 361

Pages Range: 279-292

Journal Issue: 1

DOI: 10.1016/j.ica.2007.07.018

Abstract

The reaction of dioxygen with the copper(I) complex of the tridentate ligand 1,1,4,7,7-pentamethyldiethylenetriamine (Me(5)dien) has been investigated using low-temperature stopped-flow techniques. The formation of a bis( mu-oxo)copper(III) complex as a reactive intermediate could be detected spectroscopically at low temperatures and a quantitative kinetic analysis was performed for this system. Crystal structures of the copper(II) complexes [(Me-bpa)Cu(Cl)(2)] (1), [{(Me-bpa)Cu(Cl)(ClO(4))}(2)] (2), [{(MeL)Cu(Cl)(ClO(4))}(2)] (3), and [(MeL)Cu(NCS)(2)] (4) (Me-bpa=N-methyl-[bis(2-pyridyl)methyl]amine; MeL=N-methyl-[(2-pyridyl)ethyl(2-pyridyl)methyl]amine) are reported. (c) 2007 Elsevier B.V. All rights reserved.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Indian Institute of Technology Bombay IN India (IN) Justus-Liebig-Universität Gießen DE Germany (DE)

How to cite

APA:

Astner, J., Weitzer, M., Foxon, S.P., Schindler, S., Heinemann, F.W., Mukherjee, J.,... Mukherjee, R. (2008). Syntheses, characterization, and reactivity of copper complexes with tridentate N-donor ligands. Inorganica Chimica Acta, 361(1), 279-292. https://doi.org/10.1016/j.ica.2007.07.018

MLA:

Astner, Joerg, et al. "Syntheses, characterization, and reactivity of copper complexes with tridentate N-donor ligands." Inorganica Chimica Acta 361.1 (2008): 279-292.

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