Rhodium-Phosphite SILP Catalysis for the Highly Selective Hydroformylation of Mixed C4 Feedstocks

Jakuttis M, Schönweiz A, Werner S, Franke R, Wiese KD, Haumann M, Wasserscheid P (2011)

Publication Type: Journal article

Publication year: 2011

Journal

Angewandte Chemie International Edition Wiley

Publisher: Wiley-VCH Verlag

Book Volume: 50

Pages Range: 4492--4495

Volume: 50

Issue: 19

Journal Issue: 19

DOI: 10.1002/anie.201007164

Abstract

The cat. that got the butene: Highly active and selective diphosphite ligands are applied for rhodium-catalyzed supported ionic liquid phase (SILP) hydroformylation and make it possible to form linear n-pentanal with exceptional selectivity from a mixed butene feedstock by combined isomerization and hydroformylation (see picture, vials 1--4 show typical SILP catalysts employed in this study.). The SILP catalyst is stable for more than 800h on stream.

Authors with CRIS profile

Michael Jakuttis Lehrstuhl für Chemische Reaktionstechnik Andreas Schönweiz Lehrstuhl für Chemische Reaktionstechnik Sebastian Werner Graduiertenzentrum der FAU Marco Haumann Lehrstuhl für Chemische Reaktionstechnik Peter Wasserscheid Lehrstuhl für Chemische Reaktionstechnik

Additional Organisation(s)

Exzellenz-Cluster Engineering of Advanced Materials

Involved external institutions

Evonik Degussa GmbH

Germany (DE)

How to cite

APA:

Jakuttis, M., Schönweiz, A., Werner, S., Franke, R., Wiese, K.-D., Haumann, M., & Wasserscheid, P. (2011). Rhodium-Phosphite SILP Catalysis for the Highly Selective Hydroformylation of Mixed C4 Feedstocks. Angewandte Chemie International Edition, 50(19), 4492--4495. https://dx.doi.org/10.1002/anie.201007164

MLA:

Jakuttis, Michael, et al. "Rhodium-Phosphite SILP Catalysis for the Highly Selective Hydroformylation of Mixed C4 Feedstocks." Angewandte Chemie International Edition 50.19 (2011): 4492--4495.

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