Dimerization of ethene in a fluidized bed reactor using Ni-based Supported Ionic Liquid Phase (SILP) catalysts

Kohler F, Gärtner K, Hager V, Haumann M, Sternberg M, Wang X, Szesni N, Meyer K, Wasserscheid P (2014)

Publication Type: Journal article

Publication year: 2014

Journal

Catalysis: Science and Technology Royal Society of Chemistry

Publisher: Royal Society of Chemistry

Book Volume: 4

Pages Range: 936--947

Volume: 4

Issue: 4

Journal Issue: 4

DOI: 10.1039/c3cy00905j

Abstract

The complexes [(mall)Ni(dppanis)][SbF6] (mall = methallyl, dppanis = (2-methoxyphenyl)diphenylphosphine) 1, [(mall)Ni(PPh3OC10)][SbF6] (PPh3OC10 = (2-decyloxyphenyl)diphenylphosphine) 2, and [(mall)Ni(PPh3OdiMePh)][SbF6] (PPh3OdiMePh = (2-(2,6-dimethylphenoxy)phenyl)diphenylphosphine) 3 were immobilized as Supported Ionic Liquid Phase (SILP) catalysts and applied for the tandem dimerization/isomerization of ethylene to 2-butene in a fluidized bed reactor. The better heat removal in the fluidized bed improves the catalyst stability and allows for a more detailed investigation of the deactivation mechanism. Based on kinetic studies, a second order deactivation mechanism is proposed, in which two nickel complexes dimerize if the supply of ethene is insufficient.

Authors with CRIS profile

Florian Kohler Lehrstuhl für Chemische Reaktionstechnik Konstantin Gärtner Lehrstuhl für Chemische Reaktionstechnik Veit Hager Lehrstuhl für Chemische Reaktionstechnik Marco Haumann Lehrstuhl für Chemische Reaktionstechnik Michelle Sternberg Lehrstuhl für Anorganische und Allgemeine Chemie Xinjiao Wang Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie Peter Wasserscheid Lehrstuhl für Chemische Reaktionstechnik

Additional Organisation(s)

Exzellenz-Cluster Engineering of Advanced Materials

Involved external institutions

Clariant Deutschland DE Germany (DE)

How to cite

APA:

Kohler, F., Gärtner, K., Hager, V., Haumann, M., Sternberg, M., Wang, X.,... Wasserscheid, P. (2014). Dimerization of ethene in a fluidized bed reactor using Ni-based Supported Ionic Liquid Phase (SILP) catalysts. Catalysis: Science and Technology, 4(4), 936--947. https://dx.doi.org/10.1039/c3cy00905j

MLA:

Kohler, Florian, et al. "Dimerization of ethene in a fluidized bed reactor using Ni-based Supported Ionic Liquid Phase (SILP) catalysts." Catalysis: Science and Technology 4.4 (2014): 936--947.

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