Thermally stable bis(trifluoromethylsulfonyl)imide salts and their mixtures
Scheuermeyer M, Kusche MM, Agel F, Schreiber P, Maier F, Steinrück HP, Davis JH, Heym F, Jess A, Wasserscheid P (2016)
Publication Status: Published
Publication Type: Journal article
Publication year: 2016
Journal
Publisher: Royal Society of Chemistry
Book Volume: 40
Pages Range: 7157-7161
Journal Issue: 8
DOI: 10.1039/c6nj00579a
Abstract
We show that both tetraphenylphosphonium bis(trifluoromethylsulfonyl)imide ([PPh4][NTf2]) and Cs[NTf2] are low melting salts of exceptionally high and also very similar thermal stability. This similarity indicates that the thermal stability is dominated by the anion. Moreover, eutectic mixtures of [PPh4][NTf2] and Cs[NTf2] with melting points below 100 degrees C are presented. Surface analysis of the latter in the liquid state reveals a surprising depletion of (PPh4](+) ions from the surface.
Authors with CRIS profile
Marlene Scheuermeyer
Lehrstuhl für Chemische Reaktionstechnik
Matthias Manfred Kusche
Lehrstuhl für Chemische Reaktionstechnik
Friederike Agel
Lehrstuhl für Chemische Reaktionstechnik
Patrick Schreiber
Lehrstuhl für Physikalische Chemie II
Florian Maier
Lehrstuhl für Physikalische Chemie II
Hans-Peter Steinrück
Lehrstuhl für Physikalische Chemie II
Peter Wasserscheid
Lehrstuhl für Chemische Reaktionstechnik
Additional Organisation(s)
Involved external institutions
Germany (DE)
United States (USA) (US)How to cite
APA:
Scheuermeyer, M., Kusche, M.M., Agel, F., Schreiber, P., Maier, F., Steinrück, H.-P.,... Wasserscheid, P. (2016). Thermally stable bis(trifluoromethylsulfonyl)imide salts and their mixtures. New Journal of Chemistry, 40(8), 7157-7161. https://dx.doi.org/10.1039/c6nj00579a
MLA:
Scheuermeyer, Marlene, et al. "Thermally stable bis(trifluoromethylsulfonyl)imide salts and their mixtures." New Journal of Chemistry 40.8 (2016): 7157-7161.
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