Heterolytic activation of dihydrogen at transition-metal sulfur sites in coordinatively unsaturated [Rh(L)('(bu)S4')]BF4 complexes, involving neutral hydrides, thiol hydrides, and thiol-hydride proton scrambling (L = CO, PCy3; '(bu)S4'2- = 1,2-bis[(2-mercapto-3,5-di-tert-butylphenylthiolethane2-) - Heinemann, Frank Wilhelm; et al. (Chemistry - A European Journal, 1997)
Keywords: Heterolytic cleavage; Dihydogen activation; Ligands; Hydrido complexes rhodium